Ceramics are resilient to heat and extreme environments, but they are fragile and crack easily. Recently, in a study published in Science Advances, researchers at Texas A&M University have discovered a self-healing mechanism within a type of ceramics, called MAX phases.
They have shown that these engineered ceramics form natural faults or kink bands during loading that can not only effectively stop cracks from growing but can also close and heal them, thereby preventing catastrophic failure.
Ankit Srivastava, assistant professor in the Department of Materials Science and Engineering, and a corresponding author on the study said, what's really exciting about MAX phases is that they readily form kink-bands under loading which can self-heal cracks even at room temperature, making them suitable for a variety of advanced structural applications. So far, self-healing of cracks in ceramics has only been achieved at very high temperatures by oxidation and that is why self-healing of cracks at room temperature by kink-band formation is remarkable.
This remarkable behavior of MAX phases can be traced back to their atomically layered structures.
Miladin Radovic a professor in the Department of Materials Science and Engineering and also a corresponding author of the study said, imagine a plain loaf of bread, it is homogeneous, so if I slice it up, each slice will look like the same similar in idea to conventional ceramics. But MAX phases are layered like a peanut butter sandwich with peanut butter between two slices of bread.
The researchers then investigated if this unique layered structure of MAX phases makes them any different from conventional ceramics. For their experiments, they used single-crystal samples of chromium aluminum carbide MAX phase synthesized by Thierry Ouisse of Université Grenoble Alpes, France, and a senior author of the study, and loaded them inside an electron microscope using an in-house designed test fixture.
When the researchers viewed the deforming sample in the electron microscope while applying to load, they observed that there were kink-band-like defects that formed in the material, resembling those formed in natural rocks. More interestingly, they discovered that the material within kink-bands rotates during loading which not only forms a barrier against crack propagation but also eventually closes and heals the cracks. As a consequence, the sample was no longer vulnerable to catastrophic failure.
Hemant Rathod, a doctoral student in the Department of Materials Science and Engineering and the lead author of the study said, what's really exciting is that this kinking or self-healing mechanism can occur over and over closing the newly formed cracks, thus delaying the failure of the material.
The current discovery that materials resilient to heat and extreme environments such as MAX phases, also self-heal cracks that may form during service can advance a host of next-generation technologies, for instance, efficient jet engines, hypersonic flights, and safer nuclear reactors. The researchers also noted in the current study that the kink-band induced self-healing of cracks is most likely not unique to MAX phases and can be extended to other materials with similar atomically layered structures.
Siddiq Qidwai, a program director in National Science Foundation's Directorate for Engineering said, this study demonstrates the serendipity of the scientific process. We have had self-healing soft materials and polymer composites, and now, remarkably, ceramics.
Journal Information: Hemant J. Rathod et al, Room temperature crack-healing in an atomically layered ternary carbide, Science Advances (2021). DOI: 10.1126/sciadv.abg2549